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Sorry, Wrong Umber…..Part I

You reach for a tube of Cadmium Red or Ultramarine Blue and you intuitively trust that they contain the very pigments they are named after. It’s a trust formed over years and decades of personal use, along with an assumption, an almost blind belief, that paints must surely be labeled according to definite rules. Besides, you might think, these are well-known pigments prized for their particular qualities and mentioned or recommended by almost every teacher and book on painting. Given all that, would you feel cheated or misled if you found that the colors you purchased were actually made using different pigments? That the Cadmium Red wasn’t made from cadmium red at all? That the specific properties you expected, like opacity or dry time, were lost or compromised? Would you care? We believe you would and rightfully so.

Now, for an equally and perhaps more important question – would you continue to care if that color was Burnt Sienna or Raw Umber? Or any number of other natural earths? If you find that you hesitate or waver, that you think, well, with these there might be some wiggle room, we want to passionately try to convince you otherwise. These examples are not separate – the answer to one directly informs and impacts the answer to the other. Maybe not right away, but over time the trust between manufacturer and artist will get eroded, standards and conventions will be set aside or abandoned, and the connection between a color’s name and the pigments it contains will be lost.

A Growing Problem

The scenario outlined above, concerning natural iron oxides, is unfortunately not a hypothetical, not some far-off concern to be warded off, but something that is already far too common in the here and now. More and more paints labeled with names historically reserved for natural iron oxides are turning out to contain a host of synthetic pigments. Sometimes those pigments will be blended with a natural earth, but other times the paints are made solely from synthetic pigments with not a trace of a natural iron oxide to be found. While an anomaly here or there can perhaps be tolerated or written off, the situation has reached a point where we felt it was critical to raise awareness around these issues.

The problem has also grown so large that this article focuses on only one small aspect of it; namely the inclusion of synthetic pigments that are not based on iron oxides. These are materials no one would ever expect to find in an earth color. A follow-up article will look at the much larger and more complex issue of how pigments are ultimately classified by pigment manufacturers and the Color Index, and the use of synthetic iron oxides in colors historically made from natural ones. For example, the common use of synthetic transparent red iron oxide in place of natural Burnt Sienna, or Mars Yellow in place of natural Yellow Ochre. We hope to publish that piece early next year.

Praise Where Praise Is Due

Before sharing examples of paints labeled in problematic ways, some praise is due. Many companies actually do label their paints correctly, and they should be supported and applauded for their efforts. Also, all the tubes we looked at, even ones from minor brands, did list their pigments on the label, and the information could generally be found online as well. So ultimately nothing was being hidden; artists could easily discover which pigments were being used by simply turning the tube over, or doing a quick search on a retailer’s or company’s website. And that is important to acknowledge. Go back far enough in time, and even that basic level of disclosure was not always the norm, so this alone represents something to feel good about.

The Examples

As mentioned earlier, we are highlighting only the most egregious departures from what anyone would expect to see when purchasing Raw and Burnt Umber, Raw and Burnt Sienna, or Yellow Ochre. These examples all involve the use of synthetic organic, inorganic, and complex inorganic pigments that clearly do not belong in an earth color. Synthetic organics are a class of industrially produced carbon-based pigments like the Hansas, Quinacridones, Phthalos, etc. Synthetic inorganics, besides those based on iron oxide, include things like Titanium Dioxide and Zinc Oxide, while complex inorganics are usually based on mixed metal oxides. Well-known examples of these would include Chromium Oxide and Cobalt Blues, but there are also a host of ones with names like Zinc Iron Chromite and Chrome Antimony Titanate.

Below, under each color’s heading, you will find some notes on how to recognize genuine versions of that pigment from how it is listed on the tube or in color charts so you can recognize it when purchasing paints or checking your current stock. This is followed by a table showing mixtures that used pigments other than natural and synthetic iron oxides.

The information we collected came from the websites and online color charts of easily available brands, including all the major ones. We deliberately do not share the identity of the brand behind each listing. Our purpose in writing this article is not to single out companies but to raise awareness of a general trend that impacts the industry as a whole. Even more importantly, it is to educate and inform artists on what to look for and why it matters, for ultimately you are the ones that can effect change by making your voices known to the companies you do business with. If you don’t care, the companies won’t. It is as simple as that.

Guide to Reading the Tables

Each color includes a table showing the pigments we found listed on individual tubes of oil, acrylics, and watercolors. If there was more than one example, the entries are separated by a gray stripe. Pigments in red are the ones we want to highlight in this initial survey.

Raw Umber

Genuine raw umbers should be listed as a single pigment with a Color Index Name of PBr 7. It should also have an accompanying chemical description, either on the tube or the company’s technical information, as a natural iron oxide containing manganese. This later part is important because the manganese component is an essential feature of true raw umber. Because PBr 7 can refer to a range of brown oxides, we have used its broader and more generic description of “natural brown iron oxide” whenever we could not locate a mention of manganese in the listing or company literature.

While a couple of the entries do include a natural brown iron oxide in the formula, the addition of Phthalo Green, Hansa Yellow, or Chromium Green Oxide remains problematic for a color with a long history of being solely a natural iron oxide.

Burnt Umber

True burnt umbers are calcined versions of their raw umber cousins. They should be listed as a single pigment with a Color Index of PBr 7 and description as a calcined natural iron oxide containing manganese. Again, look for the presence of “manganese” to differentiate it from other types of brown oxides.

As you will see, none of these listings come even close to that ideal. Two of the entries list Titanium White, while you can find both synthetic organics (PY139, PY150) and complex inorganics (PY164, Pbr 25) in the other ones.

Raw Sienna

Natural raw siennas can vary in how they are listed depending on their shade and source, with some pigment suppliers listing them as PY 43, natural hydrated iron oxide, and others as PBr 7, natural iron oxide. In either case, it would be shown as a single pigment rather than a blend. Under no circumstance would a natural raw sienna contain the synthetic pigments listed in red below.

Burnt Sienna

Like raw sienna, genuine burnt sienna can also be found listed in two separate ways – either as PBr 7 or PR 102. Again the difference is generally the shade of color or the way a particular supplier classifies it. In either case it would still be described as a calcined natural iron oxide. However, none of the highlighted pigments below would ever be expected in a burnt sienna.

Yellow Ochre

This natural earth color should be listed as a single pigment, PY 43, natural hydrated iron oxide, which was mentioned earlier under Raw Sienna. Unfortunately PY 42, a synthetic hydrated yellow oxide that is much more dense and opaque, is frequently being substituted for the more subtle and transparent natural one. In addition, the pigments in red clearly do not belong in a true earth color under any circumstances.

Why You Should Care and What To Do About It

The current state of affairs among earth colors can be confusing and frustrating and it appears to just be getting worse.  Long established standards for historically important earth colors are being upended and the colors replaced by a host of synthetic pigments that invariably have different properties. Labeling conventions are likewise being ignored as names once reserved for certain natural earths become, instead, mere references to a generalized type of brownish color space.

So why does this matter? Connections to historical painting techniques, color mixing recipes, materials lists handed out in classes and found in art books, all become a nightmare to navigate. A teacher recommends ‘Raw Umber’ or ‘Burnt Sienna’ and what was once an easy purchase becomes a mess of competing choices, many of which bear no resemblance to the actual colors these names are supposed to refer to. And slowly, bit by bit, the trust in labeling and paint names built up over the last many decades can start to fall apart and we find ourselves back to a time when almost anything goes as far as labeling is concerned.

And that is truly the larger and longer-term danger in all this. We might find that we get too comfortable with this type of slippery-slope loss of standards, thinking, “oh well, its just a few colors, and brown ones at that”. But if we allow these names to become untethered to their historical identities, there is really nothing to stop this eventually happening to other colors such as cadmium red, viridian green, or ultramarine blue.

As for what to do, in truth you are the best and most forceful agents of change in this. ASTM Standards can be passed and promoted, voices can be raised by some manufacturers, but it falls on artists to let those they buy from know what is important to them. If you value clear labeling, and feel that having access to genuine earth colors is important, then write, call, email, message, post or blog, but somehow let manufacturers and retailers know. And before you purchase your next earth color, turn the tube over. Check what pigments are being used. Ask questions. Let them know you want the genuine stuff.

32 Responses to Sorry, Wrong Umber…..Part I

  1. Roberta July 24, 2018 at 11:26 am #

    Thank you for your meticulous attention to this issue…I’m an old dog just new to painting (acrylics), but in classes I’ve taken I’ve actually been rebuffed for persistence in championing single pigment colors instead of the ones preferred by the instructor…one of my joys is mixing shades of secondaries, etc. from my quite limited basic palette! I rarely have good results when using colors that are already mixtures! I don’t mind being called a control freak because, hey, I don’t have all that much time and money left to mess around and end up wasting paint from failed combinations that have turned muddy!
    Again, thanks for confirming my novice suspicions!

    • Sarah Sands July 24, 2018 at 11:56 am #

      Hi Roberta –

      Thank you so much for the positive feedback and glad that the article was able to confirm your suspicions. And if there is ever anything else we can do to make your exploration of painting easier, just let us know!

  2. Michèle LaRose July 24, 2018 at 11:50 am #

    Thank you very much for your work on this issue. As an artist with a serious concern about the longevity and predictability of art materials, I have always read the labels for the pigment content and am distressed that the ASTM standards are not being respected. Is there no oversight mechanism that can fine those who flout the rules? Concerned…

    • Sarah Sands July 24, 2018 at 12:04 pm #

      Hi Michèle –

      Thank you for your reply and it is great to know that you are so passionate about this issue. That alone goes a long way to helping in the fight against the erosion of these naming conventions. Unfortunately ASTM Standards are completely voluntary, with no compliance enforcement mechanism, so as long as one is not claiming to conform to a specific ASTM Labeling Standard, they really are free to name it whatever they want. Which is all the more reason why we think the best and only hope to get companies to recommit to following a set of naming conventions is for customers to voice their concerns. But also rest assured, this is being discussed by members of ASTM and we will continue to see what we can do to educate the field. And stay tuned for our eventual Part II, where we will take more time to unpack the system and standards that dictate how pigments are classified and named.

  3. Linda July 24, 2018 at 12:17 pm #

    Dear Sarah,
    What an outstanding article! Thanks so much for raising the RED FLAG ! It is very much appreciated! I had no idea this was happening and will check my watercolor and acrylic tubes and pay attention before I buy. And if I find any offending manufacturers I will send them an email and inform the art supply store!

    • Sarah Sands July 25, 2018 at 8:39 am #

      Thanks Linda! We truly appreciate the feedback! And its great to let companies and art stores know what you value. We truly think customers have the best chance of changing the labeling practices. As we pointed out, at least everyone discloses the pigments they use, so its less about calling them out for doing something wrong and more about sharing what you would like to see. Let us know how things go and if we can help in any way.

  4. Marcao July 24, 2018 at 12:18 pm #

    In this town there are plenty of artists, but only one other pigment geek like me. We speak of colors by their color index numbers as often or more as when we speak of them using the sometimes fanciful manufacturers’ names.

    We like single pigment colors as well as blends, but we are very aware of what is in those blends. When we purchase paints, or when we are asked which paints to purchase, we go for and suggest colors based on their actual contents. In this way, I think we at least try to promote awareness of paint quality, thereby assuring we get the best product from the manufacturer that our sometimes limited budgets can afford.

    Many of our listeners or students just cover their ears and go “la la la”, but they are missing out on high quality materials. Others pay attention, and with our and their purchasing power we can weed out flawed product and force manufacturers to straighten up their act.

    • Sarah Sands July 25, 2018 at 8:43 am #

      Hi Marcao – Thanks for the comment. You are probably not alone in finding yourself as a stranded pigment geek, but how encouraging that so many painters are at least aware of the pigment numbers and use that as a guide. Just starting from there is already being far, far ahead of the game. As for the others….well, shall we say they simply live in ‘la la land’.

      🙂

  5. Jennie July 24, 2018 at 12:24 pm #

    Thank you for this information. I’ll be looking at labels more closely now. Since each paintmaker can create their own standard, Unless there is a list somewhere of best ingredients, I guess I’m going to have to learn more about chemistry.

    • Sarah Sands July 25, 2018 at 8:49 am #

      Hi Jennie – Its all a matter of baby steps, and just being more aware of labeling and the variations that you see can be helpful. Unfortunately it is true that many paint manufacturers will make there own set of rules, but ASTM does have labeling guidelines which is what we follow. We will continue to write articles on this topic, so stay tuned as there is a lot to learn and just Paint is a great place to find resources for exploring. Or feel free to throw questions our way about anything made by anybody! Truly! Just email help@goldenpaints.com and usually an answer will appear on your end by the next day (or two at most).

  6. Ernest Young July 24, 2018 at 12:51 pm #

    Hi Sarah,

    As always you are great and very helpful. I quit paying attention to “names” and paint with pigments, mainly choosing single pigment creations. The light frequencies absorbed, and those reflected, in a single pigment create a signature. When multiple pigments are combined it seems to muddy the signature.

    My favorite site is the one Bruce MacEvoy created at http://www.handprint.com/HP/WCL/water.html. I wish there was more detailed information like that in a current site. He wasn’t part of a company so was free to share his opinions.

    Thanks!

    • Sarah Sands July 25, 2018 at 8:59 am #

      Hi Ernest – Thanks for the warm feedback – that always means a lot to me. And we totally agree about the value of Bruce MacEvoy’s site. What a gift to all of as and a true labor of love. Another site i stand in amazement of is Artist Creation and their pigment database tracked across manufacturers;

      http://www.artiscreation.com/

      As much as we can tell, just a person’s passion given freely to all. There are times that examples like these gives one hope and shows the power of the internet as a storehouse of knowledge.

  7. Linda Bean July 24, 2018 at 5:04 pm #

    Thank you for the enlightening and thorough information. I have recently been confused re the labeling of ultramarine blue and French ultramarine blue. I have always believed that French ultramarine was more red. Each tube is labeled PB 29. The two tubes are from two different manufacturers.

    I’ve been surprised the sap green I buy seems to change rather often. Your article answers many questions. Thanks again.

    • Sarah Sands July 25, 2018 at 9:16 am #

      Hi Linda – Thanks for the comment and glad you found the article valuable. French Ultramarine is indeed traditionally more red. However all shades of ultramarine blue, from ones that lean green to ones that are quite warm, have PB 29 as the pigment designation. Unfortunately Color Index Names, which is what those are, are good for tracking the major aspects of a pigment but not always its specific color. Cadmiums are similar – all cadmium reds are PR 108’s but obviously they cover a range from light warm reds to dark cool ones. Anyway, long story short the world of pigments can be confusing but we are always here to help, so don’e hesitate to send us any questions to help@goldenpaints.com. We are almost always able to get a reply sent back within 8 business hours. At least that is what we aim for. In the meantime, you might find this article that we wrote on the topic of how pigments and color are described and designated by different systems helpful:

      http://www.justpaint.org/the-nomenclature-of-color/

  8. Sharon July 24, 2018 at 5:19 pm #

    I wish Golden would make water mixable oils – a medium that I recently switched to from acrylics. I love the medium, but the problem you’ve written about occurs in all the brands I’ve looked into to a fairly large degree. These crazy “not what they are called” pigment combinations can sure make for some unpleasant surprises when mixing colors! I miss the wonderful single-pigment, correctly named Golden acrylic colors in my new medium!

    • Sarah Sands July 25, 2018 at 9:38 am #

      Hi Sharon – We will certainly add your vote for water-miscible oils to our list of product ideas. And we hear you – it can get frustrating. The blends you are finding might be more prevalent in water-miscible oils because they tend to appeal to a wider range of artists beyond the more traditional oil painters – but not really sure. If nothing else, let them know. And just to be sure, have you ever given OPEN Acrylics a try? If not they could be an interesting as they provide a wonderfully long working time. But, just to be honest, still not as long as oils, and with less opacity. So always some trade-offs. Anyway, if not, we would be happy to send along some samples. And if we can help with anything else, just let us know.

  9. Jenny July 24, 2018 at 5:31 pm #

    What an appalling trend, and so unnecesssary. I’ve known for a long time that commercial paint names mean very little and that one must read labels scrupulously, especially in regard to so called cadmiums, cobalts etc which are so often nothing of the kind…. but this trend for falsifying (that’s the only word that fits, IMO) earth colours is a new low. Thanks for publicing this, Sarah!

    • Sarah Sands July 25, 2018 at 9:42 am #

      Hi Jenny – Thanks for the comment. it is a bit shocking, which is why it caught our eye. Especially some of the blends which seem so unnecessarily complex. But at least you are scrupulous about reading labels. That alone puts you well ahead of the curve. And keep an eye out for our follow-up to this piece which will be a deeper dive into some similar issues.

  10. Ivan July 25, 2018 at 6:35 am #

    I’m aware that some manufacturers use such wierd mixtures instead of real earth pigment. However, I wonder why they actually do this.

    I understand, that one might decide to use a substitute for genuine cinnabar/vermilion (PR106, mercuric sulfide), as the real thing is somewhat toxic (although I suppose no one eats his paint), has questionable lightfastness according to some sources and of course is very expensive.
    But why earths? I made few oil paints based on genuine earths myself and majority of pigments I used was really cheap, like 3,70 Euro per 100 grams.

    • Sarah Sands July 25, 2018 at 9:46 am #

      Hi Ivan –

      We totally agree and besides perhaps some advantage in controlling color variations, it does feel like taking something that is simple and inexpensive and making it into something more costly and complex. it will remain one of those enduring mysteries for now, but hopefully just making people aware that this is happening will help.

  11. Anne July 25, 2018 at 12:50 pm #

    Hi Sarah –

    Thanks for such an amazing article and thanks for caring so much about this subject. I started with the cheap paints and quickly realized that the savings weren’t at all worth the sacrifice in quality… and have been with Golden ever since. This article is so helpful for those of who aren’t chemists but want good paint.

    • Sarah Sands July 25, 2018 at 2:13 pm #

      Hi Anne! Thanks so much, both for the warm feedback but also for your support of our products and belief in what we do. That means the world to us and we never ever take it for granted. And if there is ever anything else we can do, just ask!

  12. Richard Phipps July 26, 2018 at 6:01 pm #

    A couple of questions Sarah..

    Bruce MacEvoy has said on his website regarding natural earths:

    “NOTE: The manufacture of most iron oxide artists’ paints, including those with traditional names such as “earth”, “sienna”, “umber” or “ochre”, has changed from the use of natural iron oxide clays — designated by the generic color index names PBr7 or PY43 — to the use of synthetic iron oxide powders. Small supplies of artists’ grade natural iron oxides continue to flow from mines in Europe and the Middle East, but by 2002 there were no longer any suppliers of natural iron oxide pigments registered with the Society of Dyer’s and Colourists’ (UK) Colour Index.

    Many watercolors now labeled PBr7 or PY43 are actually made of mixed synthetic iron oxide pigments, not natural ores. In fact, iron oxides used in watercolor paints today include pigments formulated for use in wood or leather stains, or as plastic, ceramic or masonry colors, and are available in a very broad range of colors and grades. See for example the page “earth tones dry pigments” at the web site of Kama Art Materials (Montréal, Québec), the mineral and iron oxide pigments available at Sinopia Pigments (San Francisco, CA) or Kremer Pigments (New York, NY), and the pigment information pages at Société des ocres de France or their USA distributor, The Earth Pigments Company (Tucson, AZ).

    The use of natural oxides has dwindled so much that in 2001 the SDC considered eliminating the color index names PBr7, PR102 and PY43 from the Colour Index, and reassigning these pigments to the color index names for synthetic brown (PBr6), red (PR101) or yellow (PY42) iron oxides. However, manufacturers lobbied to retain these color index names as convenient “color” designations and desirable marketing labels. In 2007, the SDC reaffirmed to me that they were still deliberating on the issue.”

    Second question: I have also heard (though I also don’t know if this is true) that some pigment supplies of PR102 or PY43 have some level of synthetic versions mixed in to ensure less colour variety between batches (as the impurities are what causes more colour differences in the natural versions).

    Can you comment at all on these questions?

    • Sarah Sands July 31, 2018 at 12:35 pm #

      Hi Richard – We plan to address a lot of these questions in our follow-up to this article. We purposely separated out these issues because they quickly get complicated and involve a lot of untangling of the various roles of the Color Index, pigment manufacturers, ASTM, and artist paint manufacturers when it comes to how these pigments get categorized and labeled. Certainly there appears to be some credence to the issues Bruce McEvoy raises, but in our experience it is not nearly that universal, especially among the larger natural iron oxide suppliers. The fact that none of these are registered with the Color Index means little – simply that they do not see registering with them of any business value. The Color Index, after all, does not hold the same prominence as a trade association as it did in the past. We also have not found that larger suppliers have needed to blend synthetic iron oxides with natural ones for color consistency. Rather this can be managed simply by the controlled blending of multiple lots of naturally mined earths. That said, there is definitely a market that is pursued where this is the case – such as the need for a broad palette for coloring cement or grouts, for example – but these are largely separate offerings and clearly marked. Anyway, the main thing is that yes, Bruce raises good points and it is an area that manufacturers and artists who care about this are going to need to keep tabs on, and advocate for, but at least from our perspective true natural iron oxides continue to be readily available.

      Hope that helps, but also look for our follow-up Part II to this article for a fuller picture.

      • Richard Phipps July 31, 2018 at 4:37 pm #

        Thank you Sarah 🙂

        • Sarah Sands August 2, 2018 at 1:18 pm #

          Hi Richard –

          I want to amend my earlier response as I unfortunately misrepresented some information. Indeed, it does appear that larger suppliers use synthetic iron oxides in small percentages to adjust color while still labeling their pigments with the Color Index Numbers for natural earths: PBr7, PY43, and PR102. These additions, from our understanding, can comprise up to 10% of the blend and do not significantly alter the qualities of the pigment since they are chemically identical to the main components. This practice has been true for quite some time and is not a recent development.

          There is more to unpack here, which we plan to do in the next installment to the article. It is also one of the reasons we wanted to set aside and discuss the issue of natural and synthetic iron oxides separately. In the meantime I just wanted to correct the record.

  13. Carol McIntyre July 26, 2018 at 6:25 pm #

    Hi Sarah! This is Carol McIntyre, we met recently at the conference in Boston. Thank you for your clarity and info. BTW, I speak a little to this subject in my forthcoming book “I Just Want to Paint: Mixing the Colors You Want!” Great to see it reinforced here by you, the expert.

    • Sarah Sands July 30, 2018 at 3:25 pm #

      Hi Carol! Great to touch base again since the conference in Boston. It was such a wonderful opportunity to meet people concerned with these types of questions. And there can never be too many voices raising these concerns! Maybe collectively we can all move the needle ever so slightly. or if nothing else, at least raise the level of awareness.

  14. Ted Bunker August 1, 2018 at 12:24 am #

    As some who prefers “earth colors” over the more vivid Cadmium and Quinacridones for landscapes and marine-scapes, the lack of clarity in pigmentation is fustrating in evaluation paints without purchasing them first. The [PBr7] paint-class is all over the map…so to speak. As you point out, most “earths” today are hues, not straight pigments. Plus the refinement of many pigments can skew their final hue-value-chroma, as well as their behavior when mixed with othe colors on the palette as the constiuent pigments interact. Even if their masstones are similar, their undertones can vary wildly. At least many manufacturers provide some info on their “transparency”.

    Fortunately Golden, Gamblin and a few others make the Munsell notation accessible for their paints. I just wish more manufacturers did-so.

    • Sarah Sands August 1, 2018 at 10:33 am #

      Hi Ted – We completely understand your frustration. And having the names of natural earths starting to be used for all sorts of blends is only adding to the problems that you mention, some of which are inherent to the system we have for indexing pigments and specifying colors. As you point out, even among PBr7 pigments, assuming no adulteration, you will still get a wide variation in color depending on source, processing, particle size, etc. Some of that has always been true, and the index name – Pbr7 – only speaks to the chemical composition and general color space but does not really specify a specific range of hues, much less undertones, that a PBr7 color needs to meet. Those types of specifications are done more at the level of specific industries or companies. The best advice, for now, is to try and stick to the brand or brands you rely on the most as they hopefully will be fairly consistent from batch to batch. And in the meantime, thanks for your support and appreciation. If we can do anything else to help, just ask!

  15. lad August 13, 2018 at 3:29 pm #

    Isn’t the root cause of this change due to factors like the rariety, expense, foreign sourcing or environmental costs of mining earth pigments?
    Maybe we shouldn’t use the cliche “Cheap As Dirt” anymore!

    • Sarah Sands August 16, 2018 at 3:56 pm #

      Certainly there are costs to mining natural earths, including environmental ones that are likely hard to quantify and compare to the industrial costs of producing synthetic materials. However, in terms of basic price, the synthetic iron oxides are still more expensive pound for pound; although you often need less if you chief measure is tint strength. But your points are well taken that scarcity, shipping, and environmental costs should be factored in.

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